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- W2005607246 abstract "New chiral CNN-pincer-type gold, palladium, and rhodium complexes containing N-heterocyclic carbene substituent and (S)-N-tert-butyl-methylpyrrolidine-2-carboxamide as chiral auxiliary have been synthesized and studied for asymmetric hydrogenation. The complexes were prepared by the silver carbene transfer route from the respective silver complex. The reaction with [RhCl(cod)]2 (cod = cycloocta-1,5-diene), PdCl2(CH3CN)2, or K[AuCl4] affords the corresponding cationic [Rh(cod)(ligand)]Cl, [PdCl(ligand)]Cl, and [AuCl(ligand)]Cl2 complexes in which the ligand functions effectively in a CNN coordination mode. The complexes catalyze the enantioselective hydrogenation of prochiral alkenes. Enantioselectivity is very sensitive to the NHC N-substituent, resulting in a useful switch in the predominant enantiomer." @default.
- W2005607246 created "2016-06-24" @default.
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- W2005607246 date "2009-12-11" @default.
- W2005607246 modified "2023-10-18" @default.
- W2005607246 title "Synthesis of Electron-Rich CNN-Pincer Complexes, with N-Heterocyclic Carbene and (<i>S</i>)-Proline Moieties and Application to Asymmetric Hydrogenation" @default.
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- W2005607246 doi "https://doi.org/10.1021/om900894k" @default.
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