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- W2005608698 abstract "Three conformationally preorganised host molecules based on the [3]polynorbornyl framework and incorporating di-urea receptors were synthesised and their interaction with a series of anions investigated by 1H NMR spectroscopy. A high affinity of each host molecule for dihydrogenphosphate (H2PO4−) and dihydrogenpyrophosphate (H2P2O72−) was identified. In addition to binding to the urea receptors of the host molecules, evidence for an interaction involving the non-polar C–H groups within the binding cavity of the framework and guest anions was also discovered. Furthermore, an unusual 2 : 1 host-to-anion stoichiometry was indicated when binding H2P2O72−, and a model for the anion-mediated self-assembly of this complex species is proposed." @default.
- W2005608698 created "2016-06-24" @default.
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- W2005608698 date "2007-01-01" @default.
- W2005608698 modified "2023-10-17" @default.
- W2005608698 title "Anion recognition and anion-mediated self-assembly with thiourea-functionalised fused [3]polynorbornyl frameworks" @default.
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- W2005608698 doi "https://doi.org/10.1039/b703208k" @default.
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