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- W2005614897 abstract "Solid solutions of the end members Fe2WO6, Cr2WO6, and Rh2WO6 have been prepared and their crystallographic and magnetic properties studied. All solid solutions crystallize with the trirutile structure, and their magnetic behavior is characterized by the existence of antiferromagnetic interactions and effective molar Curie constants corresponding to those expected from contributions of the spinonly moments of high-spin Fe3+, Cr3+, and diamagnetic low-spin Rh3+ ions. Fe2WO6 crystallizes with the tri-α-PbO2 structure and is antiferromagnetic and conducting. The random rutile Rh2WO6 is conducting, and the difference between its magnetic and electric properties and those of the inverse trirutile Cr2WO6 are discussed in terms of possible interactions between Cr3+(3d) or Rh3+(4d) orbitals and W6+(5d) orbitals." @default.
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- W2005614897 date "1983-05-01" @default.
- W2005614897 modified "2023-10-17" @default.
- W2005614897 title "Preparation and properties of the systems Fe2−xCrxWO6, Fe2−xRhxWO6, and Cr2−xRhxWO6" @default.
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- W2005614897 doi "https://doi.org/10.1016/0022-4596(83)90021-x" @default.
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