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• W2005620104 abstract "As the NH 2 bond angle increases, both v asym NH 2 and v sym. NH 2 increase in frequency, and the frequency separation between v asym. NH 2 and v sym. NH 2 increases as the Hammett σ p and σ m values increase (increasing electron withdrawing power). The NH 2 bond angles change with solute/solvent interaction. In CHCl 3 solution IR bands are observed for two sets of v asym. NH 2 and v sym. NH 2 frequencies. It is suggested that this is the result of intermolecular hydrogen bonding between H 2 N and HCCl 3 and between NH 2 and Cl(HCl 2 ) 2 . In CCl 4 solution the intermolecular hydrogen bonding between the NH 2 protons and the Cl atoms of CCl 4 is stronger than between the Cl atoms of CHCl 3 ." @default.
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• W2005620104 date "1992-08-01" @default.
• W2005620104 modified "2023-09-23" @default.
• W2005620104 title "Infrared Study of 4- and 3-Substituted Anilines in Hexane, Carbon Tetrachloride, or Chloroform (0.5% or Less) Solutions" @default.
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• W2005620104 doi "https://doi.org/10.1366/0003702924123863" @default.
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