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- W2005642000 abstract "Abstract The centrosymmetric monoclinic crystals of glycyl‐glycine were grown in the presence of three dipeptides (racemic and resolved Gly‐Ala, Ala‐Gly and Gly‐Leu); the presence of each yielded a different morphology. It was found by a combined theoretical and experimental study that the conformation of the guest molecule is determined by the highly stereospecific intermolecular interactions between adsorbed additive and the molecules of particular surface layers of the growing crystals. Theoretical calculations predicted the preferred conformation of the leucine side chain of Gly‐Leu consistent with the change in morphology. Occluded racemic Gly‐Leu segregates along the b axis of the single crystals of Gly‐Gly." @default.
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- W2005642000 date "1985-01-01" @default.
- W2005642000 modified "2023-10-16" @default.
- W2005642000 title "Stereochemical Discrimination at Organic Crystal Surfaces 2: The Effect of the Molecular Structure and Conformation of Dipeptides Additives on the Morphology of Glyclyglycine Crystals" @default.
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- W2005642000 doi "https://doi.org/10.1002/ijch.198500058" @default.
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