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- W2005643986 abstract "The high-temperature reaction of H atoms with C 3 F 6 was studied behind reflected shock waves in a single-pulse shock tube over the temperature range 1250–1550 K, pressures ∼16–18 atm, and residence times 500–800 μ s. The H atoms were generated by thermal decomposition of C 2 H 5 I. Gas chromatography (GC) analyses of the postshock products revealed the presence of the following species (in order of greatest yield): CF 2 CHF, CF 2 H 2 , CF 3 H, and CF 2 CH 2 . Hydrocarbons recovered in the products include C 2 H 4 , C 2 H 2 , CH 4 , traces of C 2 H 6 , and soot precursors. GC/mass spectrometry analyses of postshock products revealed trace amounts of CF 3 CH=CF 2 and CF 3 CH=CH 2 . Also detected were traces of CF 3 I, CH 3 I, C 2 H 3 I, and CHF 2 I. A kinetic model incorporating most of the above mentioned species was developed to model the experimental product yield profiles as a function of temperature. Thermochemical considerations showed that H-atom addition to the central carbon of the molecule was preferred and the deduced rate coefficient for the process was k =2×10 13 exp (−2.2 kcal mol −1 / RT ) cm 3 mol −1 , s −1 . Reaction flux analysis showed that CHF 2 I was an important intermediate and that HI was important in the formation of some hydrofluorocarbon species." @default.
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- W2005643986 date "2000-01-01" @default.
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- W2005643986 title "A shock tube kinetic study on the reaction of C3F6 and H atoms at high temperatures" @default.
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- W2005643986 doi "https://doi.org/10.1016/s0082-0784(00)80553-6" @default.
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