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- W2005657305 abstract "Abstract Characteristics of MnO y –ZrO 2 and Pt–ZrO 2 –Al 2 O 3 as reversible sorbents of NO x were investigated under dynamic changes in atmosphere. These sorbents can be used reversibly with a change of C 3 H 8 concentration in the reaction gases. Catalytic reduction of NO occurred in the presence of propane, which was more pronounced on Pt–ZrO 2 –Al 2 O 3 than on MnO y -ZrO 2 due to high activity of Pt surface for this reaction on MnO y in MnO y –ZrO 2 . The sorption was observed as soon as the atmosphere changed from a reducing to an oxidizing one. This implies that a high equilibrium partial pressure of O 2 is necessary for NO uptake since the sorbed NO − 3 species becomes stable. The beginning of NO x desorption atmospheres was somewhat dependent on the amount of stored NO x . The presence of propane in the gas phase strongly affected the characteristic sorption and desorption properties of MnO y –ZrO 2 and Pt–ZrO 2 –Al 2 O 3 . The sorption and desorption properties are different for MnO y –ZrO 2 and Pt–ZrO 2 –Al 2 O 3 , since the noble metal or metal oxide possesses unique activity for the NO reaction with C 3 H 8 and the amount of oxygen available for oxidative sorption of NO." @default.
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- W2005657305 date "1998-10-01" @default.
- W2005657305 modified "2023-09-27" @default.
- W2005657305 title "Reversible sorption–desorption of NOx by mixed oxides under various atmospheres" @default.
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- W2005657305 doi "https://doi.org/10.1016/s0920-5861(98)00256-9" @default.
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