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• W2005661340 abstract "Pipes of an unstabilized medium-density polyethylene have been pressure tested with internal stagnant water and moderately circulating air as the external medium at temperatures ranging from 70 to 105°C and changes in molecular structure and crystallinity have been studied. The stage III (fracture induced by thermal oxidation) life of the unstabilized polyethylene pipes was less than 12% of the life of the corresponding stabilized polyethylene pipes. Infrared spectroscopy and size exclusion chromatography showed an earlier and more extensive increase in the quantities of oxidation end-products and a more pronounced decrease in molar mass of the outer-wall-material than of the inner-wall-material of the pipe. Mass crystallinity, measured by differential scanning calorimetry, increased on an average by a quantity corresponding to 45 methylene groups per chain scission event. The life of the unstabilized pipe was divided into an induction period during which no detectable thermal oxidation occurred and a subsequent polymer degradation period. The induction period exhibited an Arrhenius-temperature-dependence with an activation energy of 75 kJ mol−1." @default.
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• W2005661340 date "1994-09-01" @default.
• W2005661340 modified "2023-09-28" @default.
• W2005661340 title "Degradation of unstabilized medium-density polyethylene pipes in hot-water applications" @default.
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• W2005661340 doi "https://doi.org/10.1002/pen.760341708" @default.
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