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- W2005663007 abstract "Abstract The retention characteristics of 11 ether-based and 2 iodinated halocarbon fluids related to alternative refrigerant research have been studied as a function of temperature on a stationary phase consisting of a 5% (by mass) coating of a low-molecular-mass polymer of hexafluoropropylene epoxide on a graphitized carbon black adsorbent. Measurements were performed at 0, 20, 40, 60, and 80°C for R-E125 and R-E134; at 40, 60, 80, and 100°C for R-E143a, R-CE216, R-E236ea1, R-E245fa1, R-E263fb1, and R13I-1; at 80, 100, 120, and 140°C for R-E235ca2, R-E235da1, R-E347, and R-217I-1; and at 100, 120, 140, and 160°C for R-E280. Measurements were attempted for several other more chlorinated ether-based compounds, but the chromatographic conditions could not be optimized sufficiently to allow standard retention parameters to be measured reliably. Relative retentions as a function of temperature were calculated with respect to the retentions of tetrafluoromethane (R-14) and hexafluorethane (R-116). Qualitative features of the data are examined, and trends are identified. In addition, the relative retention data were fitted to linear models for the purpose of predicting retention behavior of these compounds to facilitate chromatographic analysis." @default.
- W2005663007 created "2016-06-24" @default.
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- W2005663007 date "1996-06-01" @default.
- W2005663007 modified "2023-09-26" @default.
- W2005663007 title "Retention of halocarbons on a hexafluoropropylene epoxide modified graphitized carbon black Part 6: Eleven fluoroethers and two iodofluoroalkanes" @default.
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- W2005663007 doi "https://doi.org/10.1016/0021-9673(95)01325-3" @default.
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