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- W2005676845 abstract "Three accessible azobenzene mesogen-substituted diacetylene monomers (DA1, DA2, and DA3) were synthesized and the effect of the molecular structure on the photopolymerization behavior and self-assembled structures of the resulting azobenzene-substituted polydiacetylene (PDA) films had been investigated in detail. The films derived from DA1 were substantially polymerized into blue phase. However, the films derived from DA2 and DA3 were polymerized into red phase directly. The morphology, packing structure, and thermal stability of the resulting azobenzene-substituted PDA films were characterized in detail by SEM, XRD as well as POM measurements. PDA1 formed micrometer-sized lamellar crystal structures, while PDA2 and PDA3 both formed spherulitic crystal structures. The strong π-π stacking interaction among side chains was essential for maintaining high stability upon thermal stimulus." @default.
- W2005676845 created "2016-06-24" @default.
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- W2005676845 date "2010-02-03" @default.
- W2005676845 modified "2023-09-23" @default.
- W2005676845 title "Molecular Structure Modulated Organization and Properties of Azobenzene-Substituted Polydiacetylene Assemblies Films: Photopolymerization, Morphology, and Thermal Stability" @default.
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- W2005676845 doi "https://doi.org/10.1002/macp.200900513" @default.
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