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- W2005678897 abstract "Our aim in this paper is to study classical dynamics in two-level molecular systems. We first derive, through the Wigner phase-space transform, a classical limit that reduces unfortunately to the adiabatic approximation. This lead us to develop a one-center quantal approximation whose variables can be interpreted in a fully classical Hamiltonian scheme. As a prominent feature, this Hamiltonian couples polarization and spatial motion. We apply it successfully to the Rosenthal-Stuckelberg oscillations. We analyze one-dimensional diffusion similar to a molecular reaction, it appears to exhibit chaotic behavior." @default.
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- W2005678897 modified "2023-10-18" @default.
- W2005678897 title "Nonadiabatic effects in two-level systems: A classical analysis" @default.
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- W2005678897 doi "https://doi.org/10.1103/physreva.50.1409" @default.
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