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- W2005690895 abstract "Abstract In this work we have determined the surface composition of small supported Pt-Ni alloy particles (diameter 2–5 nm) by means of infrared spectra of adsorbed CO and NO. By dosing carbon monoxide and nitric oxide in the appropriate sequence to the alloys, carbon monoxide is adsorbed selectively on the Pt atoms and nitric oxide on the Ni atoms. On the alloy surfaces no reaction occurs between these adsorbed species as the bands observed do not change upon standing in vacuo. With increasing bulk nickel concentration the intensity of the CO/Pt band drops, whereas the intensity of the NO/Ni band increases. Also the band maximum of the CO/Pt band shifts continuously to lower wavenumbers and the shape of the NO/Ni band changes. It is concluded that the composition of the surface is almost equal to that of the bulk." @default.
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- W2005690895 title "The surface composition of silica-supported Pt-Ni alloys" @default.
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- W2005690895 doi "https://doi.org/10.1016/0169-4332(86)90058-9" @default.
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