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- W2005702555 abstract "A novel silver-containing compound, bis(benzylamino)silver(I) benzylcarbamate, with an unusual molecular structure is easily synthesized by the reaction of benzylammonium benzylcarbamate and silver oxide. It crystallizes in the triclinic crystal system with the space group Pbar 1 with a = 5.2006 (5), b = 14.6298 (15), c = 14.7246 (15) Å, α = 68.729 (2), β = 83.507 (2), γ = 85.412 (2)° and Z = 2. In the crystal, one Ag atom coordinates with the two amino groups in two benzylamine molecules, and there are no silver–silver and silver–oxygen interactions. The carboxylate groups take part in balancing the electric charge and forming hydrogen bonds. Both the compound and the starting material benzylammonium benzylcarbamate exhibit room-temperature solid-state emissions with the peaks at 300 and 406 nm, respectively." @default.
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- W2005702555 date "2012-07-17" @default.
- W2005702555 modified "2023-09-26" @default.
- W2005702555 title "Synthesis, structure and spectroscopic properties of a novel compound bis(benzylamino)silver(I) benzylcarbamate" @default.
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- W2005702555 doi "https://doi.org/10.1107/s0108768112030212" @default.
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