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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2005751906> ?p ?o ?g. }

• W2005751906 endingPage "1918" @default.
• W2005751906 startingPage "1911" @default.
• W2005751906 abstract "A concise synthesis of naphthalene compounds for incorporation into a synthetic sequence for the rubromycin family of natural products is presented. These highly substituted naphthalenes are generated in seven and nine steps, respectively, from 2,4,5-trimethoxybenzaldehyde. Three ring-forming methods were explored and the controlled oxygenation of different positions was investigated to yield differentially substituted/protected systems. Key steps to the final products include a Stobbe condensation to form the ring system and a novel series of regioselective oxidations to introduce the required oxygen functionality. These naphthalene products incorporate orthogonal protecting groups and are suitable for combination with a variety of coupling partners." @default.
• W2005751906 created "2016-06-24" @default.
• W2005751906 creator A5003847416 @default.
• W2005751906 creator A5046150502 @default.
• W2005751906 creator A5052701906 @default.
• W2005751906 date "2008-02-08" @default.
• W2005751906 modified "2023-10-07" @default.
• W2005751906 title "A Concise Synthesis of the Naphthalene Portion of Purpuromycin" @default.
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• W2005751906 doi "https://doi.org/10.1021/jo7024114" @default.
• W2005751906 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18257585" @default.
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