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- W2005758450 abstract "Carba-α- and β-d-galactose derivatives were efficiently prepared from a cyclohex-3-ene-1,2-diol derivative 1. Regioselective inversion of 2-OH, and stereoselective dihydroxylation of 1 were accomplished to provide a carba-β-d-galactose derivative 6 in a good yield and with a high stereoselectivity. Stereo-inversion of 1-OH of 6 via oxidation/reduction gave carba-α-d-galactose derivative 12 with a high stereoselectivity. An efficient coupling of carba-α-galactose 12 with an aziridine derivative of sphingosine has been demonstrated to give 1-O-carba-α-galactosyl sphingosine derivative 14." @default.
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- W2005758450 date "2006-11-01" @default.
- W2005758450 modified "2023-09-23" @default.
- W2005758450 title "Practical syntheses of optically active carbagalactose and their potential application to the carbocyclic analogues of KRN7000" @default.
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- W2005758450 doi "https://doi.org/10.1016/j.tetasy.2006.11.014" @default.
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