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- W2005774066 abstract "The recombination kinetics of three photogenerated covalently-linked ketyl-phenoxyl triplet radical pairs,3[PhC.(OD)C6H4O(CH2)nOC6H4C6H4O.] (n=3, 6, and 10), and of the corresponding deuterated derivatives were examined by the laser flash technique under an external magnetic field (up to 0.2 T) in a CDCl3/CD3OD (2∶1) mixture. In zero magnetic field, radical pairs (RPs) with small exchange interactions (n=6 and 10) are characterized by high values of the magnetic isotope effect (MIE), which reach 3 for pairs withn=10. Under strong magnetic fields (up to 0.2 T), the values of MIE decrease to 1.2 to 1.1. The photochemical behavior of covalently-linked RPs is compared with that of similar unlinked RPs in micelles." @default.
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- W2005774066 date "1994-10-01" @default.
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- W2005774066 title "Magnetic field and magnetic isotope effects on the recombination kinetics of chain-linked ketyl-phenoxyl triplet radical pairs" @default.
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- W2005774066 doi "https://doi.org/10.1016/0009-2614(94)00947-3" @default.
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