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- W2005775469 abstract "Abstract Reactions of [RUCl 2 ( η 6 -arene)] 2 with ammonium salt of dialkyldithiophosphoric acid in 1 : 1 and 1: 2 stoichiometry readily gave complexes of the type [Ru{SSP(OR) 2 }(Cl( η 6 -arene)] (arene = benzene, p-cymene; R = Et, n Pr, i Pr, n Bu o s Bu) and [Ru{SSP(OR) 2 } 2 ( η 6 -arene)] (R = Et; arene = p-cymene). The former complexes, on treatment with NaBPh 4 in acetone followed by addition of a neutral donor ligand (L), afforded cationic complexes [Ru{SSP(OEt) 2 }(η 6 -p-cymene)L][BPh 4 ] ( L = py , PPh 3 , (p-FC 6 H 4 ) 3 P, AsPh 3 ]. All the complexes were characterized by elemental analysis and NMR ( 1 H, 31 P) data. A single crystal X-ray structure determination of [Ru{SSP(OEt) 2 (η 6 -p-cymene(PPh 3 )][BPh 4 ] has established an octahedral configuration around the ruthenium atom. The structure consists of a ruthenium centre bonded to an η 6 -p-cymene, a chelated dithiophosphate and a unidentate triphenylphosphine ligand." @default.
- W2005775469 created "2016-06-24" @default.
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- W2005775469 title "Synthesis and characterization of areneruthenium(II) dialkyldithiophosphate complexes: single crystal structure of [Ru{SSP(OEt)2}(η6-p-cymene)(PPh3)][BPh4]" @default.
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- W2005775469 doi "https://doi.org/10.1016/0022-328x(95)06062-2" @default.
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