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- W2005785093 abstract "The production of Cl− ions has been studied in atmospheric-pressure premixed flames of H2 or C2H2 with O2 and N2 over the temperature range 1810–2750K. Ion concentrations were measured by continuously sampling a fraction of a flame into a mass spectrometer. The observations indicate that the two processes: HCl+e−⇄k−1k1Cl−+H account for the production and disappearance of Cl− ions in these systems. There is clear evidence that the rates of these two opposing steps are fast enough to equal one another, so that the overall reaction is equilibrated everywhere in each flame. The consequence of this state of affairs is that reaction (I) is shifted, as the temperature falls during flame sampling, in the direction that Cl− ions disappear. It proved possible to measure the extent of this loss of Cl− by reaction (I) adjusting to local conditions during sampling. This in turn enabled the rate constants k1 and k−1 to be measured from observations over a wide range of conditions. The results indicate that: k1=7±5×10−4T−1exp(−9500/T) k−1=7±5×10−10" @default.
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- W2005785093 date "1975-01-01" @default.
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- W2005785093 title "The kinetics of formation of chloride ions in atmospheric-pressure flames by HC1+e−→Cl−+H" @default.
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- W2005785093 doi "https://doi.org/10.1016/s0082-0784(75)80363-8" @default.
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