Matches in SemOpenAlex for { <https://semopenalex.org/work/W2005803263> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2005803263 endingPage "215" @default.
- W2005803263 startingPage "209" @default.
- W2005803263 abstract "The reactions of octahedral bis[2(1-methyl-2-oxo- propylidenehydrazine - S -methylcarbodithioato) NSO - (-1)]nickel(II) (3, R = CH 3 ) with aromatic heterocyclicamines (pyridine, 3- and 4-methylpyridine), secondary aliphatic amines (diethyl, di-n-propyl and di- n-butylamine) and alicyclic amines (piperidine and morpholine) have been studied in benzene. Spectrophotometric studies revealed that these reactions proceed by nucleophilic displacement of the two coordinated carbonyl oxygens to give the corresponding bis(amine) adducts. The kinetic measurements of these reactions indicate first-order dependence on the substrate and second-order dependence on the amine concentration. A comparison of the activation parameters suggests the formation of a π adduct in the transition state in the case of the pyridines. In the case of the secondary aliphatic amines, hydrophobic interactions between the alkyl chains and the in-plane ligand is proposed." @default.
- W2005803263 created "2016-06-24" @default.
- W2005803263 creator A5028888319 @default.
- W2005803263 creator A5041026832 @default.
- W2005803263 creator A5088588759 @default.
- W2005803263 date "1989-06-01" @default.
- W2005803263 modified "2023-09-23" @default.
- W2005803263 title "Reactivity of metal chelates of sulphur containing ligands towards lewis bases. Part IV. Reaction of bis [2(1-methyl-2-oxo-propylidenehydrazine-S- methylcarbodithioato)NSO(-1) ] nickel(II) with amines" @default.
- W2005803263 cites W1578195275 @default.
- W2005803263 cites W1970375866 @default.
- W2005803263 cites W1974172250 @default.
- W2005803263 cites W1976876595 @default.
- W2005803263 cites W1989730023 @default.
- W2005803263 cites W2036709368 @default.
- W2005803263 cites W2040388021 @default.
- W2005803263 cites W2048383141 @default.
- W2005803263 cites W2057931082 @default.
- W2005803263 cites W2080573370 @default.
- W2005803263 cites W2081868042 @default.
- W2005803263 cites W2318068990 @default.
- W2005803263 cites W2323827937 @default.
- W2005803263 cites W2333894488 @default.
- W2005803263 cites W2334497148 @default.
- W2005803263 doi "https://doi.org/10.1016/s0020-1693(00)80588-5" @default.
- W2005803263 hasPublicationYear "1989" @default.
- W2005803263 type Work @default.
- W2005803263 sameAs 2005803263 @default.
- W2005803263 citedByCount "2" @default.
- W2005803263 crossrefType "journal-article" @default.
- W2005803263 hasAuthorship W2005803263A5028888319 @default.
- W2005803263 hasAuthorship W2005803263A5041026832 @default.
- W2005803263 hasAuthorship W2005803263A5088588759 @default.
- W2005803263 hasConcept C108204754 @default.
- W2005803263 hasConcept C131779359 @default.
- W2005803263 hasConcept C142724271 @default.
- W2005803263 hasConcept C155647269 @default.
- W2005803263 hasConcept C161790260 @default.
- W2005803263 hasConcept C163638829 @default.
- W2005803263 hasConcept C178790620 @default.
- W2005803263 hasConcept C178907741 @default.
- W2005803263 hasConcept C185592680 @default.
- W2005803263 hasConcept C188027245 @default.
- W2005803263 hasConcept C204787440 @default.
- W2005803263 hasConcept C206263279 @default.
- W2005803263 hasConcept C2776910235 @default.
- W2005803263 hasConcept C2777691172 @default.
- W2005803263 hasConcept C2779485729 @default.
- W2005803263 hasConcept C2780263894 @default.
- W2005803263 hasConcept C2781056017 @default.
- W2005803263 hasConcept C2781462491 @default.
- W2005803263 hasConcept C71924100 @default.
- W2005803263 hasConceptScore W2005803263C108204754 @default.
- W2005803263 hasConceptScore W2005803263C131779359 @default.
- W2005803263 hasConceptScore W2005803263C142724271 @default.
- W2005803263 hasConceptScore W2005803263C155647269 @default.
- W2005803263 hasConceptScore W2005803263C161790260 @default.
- W2005803263 hasConceptScore W2005803263C163638829 @default.
- W2005803263 hasConceptScore W2005803263C178790620 @default.
- W2005803263 hasConceptScore W2005803263C178907741 @default.
- W2005803263 hasConceptScore W2005803263C185592680 @default.
- W2005803263 hasConceptScore W2005803263C188027245 @default.
- W2005803263 hasConceptScore W2005803263C204787440 @default.
- W2005803263 hasConceptScore W2005803263C206263279 @default.
- W2005803263 hasConceptScore W2005803263C2776910235 @default.
- W2005803263 hasConceptScore W2005803263C2777691172 @default.
- W2005803263 hasConceptScore W2005803263C2779485729 @default.
- W2005803263 hasConceptScore W2005803263C2780263894 @default.
- W2005803263 hasConceptScore W2005803263C2781056017 @default.
- W2005803263 hasConceptScore W2005803263C2781462491 @default.
- W2005803263 hasConceptScore W2005803263C71924100 @default.
- W2005803263 hasIssue "2" @default.
- W2005803263 hasLocation W20058032631 @default.
- W2005803263 hasOpenAccess W2005803263 @default.
- W2005803263 hasPrimaryLocation W20058032631 @default.
- W2005803263 hasRelatedWork W1663062043 @default.
- W2005803263 hasRelatedWork W1984276037 @default.
- W2005803263 hasRelatedWork W2014345271 @default.
- W2005803263 hasRelatedWork W2026948689 @default.
- W2005803263 hasRelatedWork W2045532829 @default.
- W2005803263 hasRelatedWork W2057403514 @default.
- W2005803263 hasRelatedWork W2134967019 @default.
- W2005803263 hasRelatedWork W2951983131 @default.
- W2005803263 hasRelatedWork W2997957958 @default.
- W2005803263 hasRelatedWork W4243601509 @default.
- W2005803263 hasVolume "160" @default.
- W2005803263 isParatext "false" @default.
- W2005803263 isRetracted "false" @default.
- W2005803263 magId "2005803263" @default.
- W2005803263 workType "article" @default.