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- W2005811161 abstract "The activity coefficients at infinite dilution, γ13∞, for 59 solutes, including alkanes, cycloalkanes, alkenes, alkynes, aromatic hydrocarbons, alcohols, water, acetic acid, thiophene, ethers, ketones, esters, butanal 4, and acetonitrile in the ionic liquid 1-hexyl-3-methylimidazolium tetracyanoborate, [HMIM][TCB], were determined by gas–liquid chromatography at six temperatures over the range (318.15 to 368.15) K. The partial molar excess Gibbs free energies ΔG1E,∞, enthalpies ΔH1E,∞, and entropies ΔS1E,∞ at infinite dilution were calculated from the experimental γ13∞ values obtained over the temperature range. The gas–liquid partition coefficients, KL were calculated for all solutes. The selectivities for different separation problems were calculated from γ13∞ and compared to literature values for N-methyl-2-pyrrolidinone (NMP), sulfolane, and other tetracyanoborate-based ionic liquids. The densities of [HMIM][TCB] within the temperature range from 318.15 K to 368.15 K were measured." @default.
- W2005811161 created "2016-06-24" @default.
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- W2005811161 date "2012-04-01" @default.
- W2005811161 modified "2023-10-17" @default.
- W2005811161 title "Measurements of activity coefficients at infinite dilution for organic solutes and water in the ionic liquid 1-hexyl-3-methylimidazolium tetracyanoborate" @default.
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- W2005811161 doi "https://doi.org/10.1016/j.jct.2011.11.025" @default.
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