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- W2005859093 abstract "The trans and cis forms of 3- and 4-stillbazole oxide and trans-2-(p-methoxystyryl)pyridine oxide have been prepared from the corresponding stilbazoles, by addition of HClO and HBrO, followed by dehydrohalogenation of the halohydrins with base. The configurations of the epoxides have been confirmed by their NMR spectra. The stereochemistry of the ring opening of the above mentioned compounds with HCl, HBr and CCl3COOH has been investigated and compared with that of the similar reactions of the stilbene oxides, very pronounced differences in steric course being observed. The reactions of the stilbazole oxides with the hydrogen halides take place with complete inversion, those with CCl3COOH with decreasing degrees of inversion in going from the 2- to the 3- and to the 4-pyridyl derivatives." @default.
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- W2005859093 date "1968-01-01" @default.
- W2005859093 modified "2023-09-26" @default.
- W2005859093 title "Stereochemistry of the ring opening of some stilbazole oxides" @default.
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- W2005859093 doi "https://doi.org/10.1016/s0040-4020(01)82501-1" @default.
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