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• W2005866234 abstract "Abstract Thermal decomposition of bis(trifluoromethyl) peroxydicarbonate has been studied. The mechanism of decomposition is a simple bond fission, homogeneous first‐order process when the reaction is carried out in the presence of inert gases such as N 2 or CO. An activation energy of 28.5 kcal mol −1 was determined for the temperature range of 50–90°C. Decomposition is accelerated by nitric oxide because of a chemical attack on the peroxide forming substances different from those formed with N 2 or CO. An interpretation on the influence of the substituents in different peroxides on the OO bond is given. © 2002 Wiley Periodicals, Inc. Int J Chem Kinet 35: 15–19, 2003" @default.
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• W2005866234 date "2002-10-30" @default.
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• W2005866234 title "Kinetics of the thermal decomposition of bis(trifluoromethyl) peroxydicarbonate, CF₃OC(O)OOC(O)OCF₃" @default.
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• W2005866234 doi "https://doi.org/10.1002/kin.10099" @default.
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