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- W2005872912 abstract "Abstract Rates of hydrogenolysis, r H , of neopentane have been measured on supported metal catalysts containing Ru, Rh, Pd, Os, Ir, Pt, and Au. At 250 °C, values of r H , referred to unit surface area of the metal, differ by 10 orders of magnitude, Au being the least active and Ru the most active metal investigated. The order of activity can be correlated with Pauling's percentage d -bond character. Among all metals of Group VIII plus Cu and Au, only Ir, Pt, and Au are found to isomerize neopentane to isopentane. They do so with comparable selectivity. It is speculated that the exceptional ability of these three metals to isomerize neopentane is related to their high electronegativity and to a readily shifted surface valency as a result of promotion of d electrons to empty s levels." @default.
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- W2005872912 date "1970-01-01" @default.
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- W2005872912 title "Reactions of neopentane on transition metals" @default.
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- W2005872912 doi "https://doi.org/10.1016/0021-9517(70)90199-5" @default.
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