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- W2005890643 abstract "Ru K-edge XAS data indicate that second generation ruthenium-based olefin metathesis precatalysts (L = N-heterocyclic carbene) possess a more electron-deficient metal center than in the corresponding first generation species (L = tricyclohexylphosphine). This surprising effect is also observed from DFT calculations and provides a simple rationale for the slow phosphine dissociation kinetics previously noted for second-generation metathesis precatalysts." @default.
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- W2005890643 date "2007-11-30" @default.
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- W2005890643 title "An Electronic Rationale for Observed Initiation Rates in Ruthenium-Mediated Olefin Metathesis: Charge Donation in Phosphine and N-Heterocyclic Carbene Ligands" @default.
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- W2005890643 doi "https://doi.org/10.1021/ja0747674" @default.
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