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- W2005907105 abstract "The emission spectrum of ZrCl has been observed in the 1800–12 000 cm−1 region using a Fourier transform spectrometer. The molecules were excited in a microwave discharge of a mixture of helium and a trace of ZrCl4 vapor. In addition to the C4Δ–X4Φ transition reported previously, numerous new bands observed in the near infrared have been classified into two electronic transitions, [7.3]2Δ–a2Φ and [9.4]2Φ–a2Φ. Five new bands observed in the 6700–7400 cm−1 region have been assigned as 2Δ3/2–2Φ5/2 and 2Δ5/2–2Φ7/2 subbands of a new electronic transition, [7.3]2Δ–a2Φ. The two subbands of the [9.4]2Φ–a2Φ transition were previously observed by G. Phillips, S. P. Davis, and D. C. Galehouse [Astrophys. J. Suppl. 43, 417–434 (1980)], who tentatively labeled them as 2Π1/2–2Π1/2 and 2Π3/2–2Π3/2 subbands. A number of new bands involving higher vibrational levels have been identified for these two subbands. A rotational analysis of a number of bands of both transitions has been obtained and spectroscopic constants have been determined. Global perturbations have been observed in both spin components of the a2Φ state. The assignment of the observed electronic states has been discussed in light of recent theoretical calculations." @default.
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- W2005907105 title "Fourier Transform Emission Spectroscopy of the [7.3]2Δ–a2Φ and [9.4]2Φ-a2Φ Systems of ZrCl" @default.
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- W2005907105 doi "https://doi.org/10.1006/jmsp.1999.7886" @default.
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