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- W2005920229 abstract "Abstract A procedure has been developed which can be used to calculate the contribution of the enthalpy of lattice expansion to the partial molar enthalpy of hydrogen in body-centred cubic metals. Values for the enthalpy of lattice expansion fall in the range 100 – 200 kJ (mol H 2 ) −1 . Variations in this term are mainly attributable to differences in the bulk modulus of the metals. Variation in the lattice parameter of the metals has been considered and shown not to be responsible for the variation in the partial molar enthalpy. A comparison is made of the relative importance of geometric and electronic contributions to the partial molar enthalpy, from which it is concluded that the electronic term is dominant. Using the values calculated for the enthalpy of lattice expansion it is shown that differences between enthalpies of adsorption and enthalpies of absorption are not due to the enthalpy required to expand the metal lattice." @default.
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- W2005920229 date "1979-01-01" @default.
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- W2005920229 title "The relative importance of geometric and electronic contributions to the thermodynamic properties of bodycentred cubic metal hydrides" @default.
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- W2005920229 doi "https://doi.org/10.1016/0022-5088(79)90208-x" @default.
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