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- W2005953209 abstract "Abstract Simple aldimine, derived from p ‐nitrobenzaldehyde and 2‐aminophenol, reacts with allyltrichlorosilane in the presence of chiral N ‐formylproline activator 5 and an L ‐proline additive to afford the corresponding homoallylic amine in good yield (84 %) and with moderate enantioselectivity (43 % ee ). The role of the second formamide moiety in the activator is crucial to bring about the enhancement in the reaction rate and enantioselectivity, as C 2 ‐chiral bisformamide 1 promotes for the same allylation reaction in higher yield (94 %) and enantioselectivity (83 % ee ). Chiral monoformamide 5 (10 mol‐%), with the assistance of HMPA as an additive, also catalyses the asymmetric reduction of ketimine 13 in the presence of trichlorosilane in good yield and enantioselectivity (75 %, 81 % ee ). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
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- W2005953209 date "2007-05-10" @default.
- W2005953209 modified "2023-10-17" @default.
- W2005953209 title "Organocatalysis with Chiral Formamides: Asymmetric Allylation and Reduction of Imines" @default.
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- W2005953209 doi "https://doi.org/10.1002/ejoc.200700058" @default.
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