Matches in SemOpenAlex for { <https://semopenalex.org/work/W2005994472> ?p ?o ?g. }
- W2005994472 endingPage "7821" @default.
- W2005994472 startingPage "7812" @default.
- W2005994472 abstract "A synthesis of the ABC-rings of the polyketide natural product hexacyclinic acid has been achieved. The B-ring was formed first via an intramolecular ester-tethered Diels−Alder reaction, and the A-ring was annulated to this by means of a SmI2 mediated reductive 5-exo-trig cyclization of a samarium−ketyl radical onto a vinyl group. Finally, the C-ring was closed using olefin metathesis. Interestingly, use of enyne metathesis resulted in the synthesis of a more functionalized 5-membered C-ring in a model system, but an undesired 6-membered C-ring in the actual system. An investigation of this change in selectivity is discussed." @default.
- W2005994472 created "2016-06-24" @default.
- W2005994472 creator A5007552871 @default.
- W2005994472 creator A5009282940 @default.
- W2005994472 creator A5029385341 @default.
- W2005994472 creator A5037081452 @default.
- W2005994472 creator A5045396939 @default.
- W2005994472 creator A5067302060 @default.
- W2005994472 creator A5072671518 @default.
- W2005994472 date "2009-09-24" @default.
- W2005994472 modified "2023-10-09" @default.
- W2005994472 title "Studies on the Synthesis of the ABC Rings of (±)-Hexacyclinic Acid" @default.
- W2005994472 cites W1963982778 @default.
- W2005994472 cites W1978146774 @default.
- W2005994472 cites W1988942058 @default.
- W2005994472 cites W1993372864 @default.
- W2005994472 cites W2010180630 @default.
- W2005994472 cites W2012678399 @default.
- W2005994472 cites W2013014478 @default.
- W2005994472 cites W2013711420 @default.
- W2005994472 cites W2026302114 @default.
- W2005994472 cites W2026485307 @default.
- W2005994472 cites W2034049877 @default.
- W2005994472 cites W2059858640 @default.
- W2005994472 cites W2061064098 @default.
- W2005994472 cites W2063440565 @default.
- W2005994472 cites W2065769178 @default.
- W2005994472 cites W2067492813 @default.
- W2005994472 cites W2072028543 @default.
- W2005994472 cites W2073304751 @default.
- W2005994472 cites W2103169163 @default.
- W2005994472 cites W2109739606 @default.
- W2005994472 cites W2110469424 @default.
- W2005994472 cites W2125006716 @default.
- W2005994472 cites W2148127071 @default.
- W2005994472 cites W2156607919 @default.
- W2005994472 cites W2162126973 @default.
- W2005994472 cites W2176872597 @default.
- W2005994472 cites W2949335583 @default.
- W2005994472 cites W2949437432 @default.
- W2005994472 cites W2949575426 @default.
- W2005994472 cites W2949596960 @default.
- W2005994472 cites W2951114269 @default.
- W2005994472 cites W2952337023 @default.
- W2005994472 cites W2952539107 @default.
- W2005994472 cites W2952882308 @default.
- W2005994472 cites W2952998165 @default.
- W2005994472 doi "https://doi.org/10.1021/jo901547k" @default.
- W2005994472 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19813768" @default.
- W2005994472 hasPublicationYear "2009" @default.
- W2005994472 type Work @default.
- W2005994472 sameAs 2005994472 @default.
- W2005994472 citedByCount "11" @default.
- W2005994472 countsByYear W20059944722012 @default.
- W2005994472 countsByYear W20059944722013 @default.
- W2005994472 countsByYear W20059944722015 @default.
- W2005994472 countsByYear W20059944722017 @default.
- W2005994472 countsByYear W20059944722021 @default.
- W2005994472 countsByYear W20059944722022 @default.
- W2005994472 crossrefType "journal-article" @default.
- W2005994472 hasAuthorship W2005994472A5007552871 @default.
- W2005994472 hasAuthorship W2005994472A5009282940 @default.
- W2005994472 hasAuthorship W2005994472A5029385341 @default.
- W2005994472 hasAuthorship W2005994472A5037081452 @default.
- W2005994472 hasAuthorship W2005994472A5045396939 @default.
- W2005994472 hasAuthorship W2005994472A5067302060 @default.
- W2005994472 hasAuthorship W2005994472A5072671518 @default.
- W2005994472 hasConcept C139066938 @default.
- W2005994472 hasConcept C153914509 @default.
- W2005994472 hasConcept C161790260 @default.
- W2005994472 hasConcept C172456720 @default.
- W2005994472 hasConcept C178790620 @default.
- W2005994472 hasConcept C185592680 @default.
- W2005994472 hasConcept C20327893 @default.
- W2005994472 hasConcept C2778128264 @default.
- W2005994472 hasConcept C2780378348 @default.
- W2005994472 hasConcept C2780588603 @default.
- W2005994472 hasConcept C35753019 @default.
- W2005994472 hasConcept C44228677 @default.
- W2005994472 hasConcept C51886252 @default.
- W2005994472 hasConcept C521977710 @default.
- W2005994472 hasConcept C536819264 @default.
- W2005994472 hasConcept C71240020 @default.
- W2005994472 hasConcept C75079739 @default.
- W2005994472 hasConceptScore W2005994472C139066938 @default.
- W2005994472 hasConceptScore W2005994472C153914509 @default.
- W2005994472 hasConceptScore W2005994472C161790260 @default.
- W2005994472 hasConceptScore W2005994472C172456720 @default.
- W2005994472 hasConceptScore W2005994472C178790620 @default.
- W2005994472 hasConceptScore W2005994472C185592680 @default.
- W2005994472 hasConceptScore W2005994472C20327893 @default.
- W2005994472 hasConceptScore W2005994472C2778128264 @default.
- W2005994472 hasConceptScore W2005994472C2780378348 @default.
- W2005994472 hasConceptScore W2005994472C2780588603 @default.
- W2005994472 hasConceptScore W2005994472C35753019 @default.
- W2005994472 hasConceptScore W2005994472C44228677 @default.
- W2005994472 hasConceptScore W2005994472C51886252 @default.
- W2005994472 hasConceptScore W2005994472C521977710 @default.