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- W2005998541 abstract "Abstract The deactivation of O 2 ( 1 Δ g ) by ground-state O 2 was investigated by the direct time-resolved phosphorescence technique in four perhalogenated solvents at 295 K. A very strong isotope effect of k 16 Q / k 18 Q =70 was observed on the quenching rate constant, which is reproduced by the model developed by Maier, Wild, Klingshirn and Plotz for O 2 ( 1 Δ g ) deactivation in pure O 2 . Thus, solvent molecules do not support quenching by O 2 . k 16 Q ranges from 2600 M −1 s −1 in perfluorohexane to 4100 M −1 s −1 in perflourodecalin and is about three times larger than in gaseous 16 O 2 . The variation of k 16 Q correlates with changes in the packing fraction of the solvents." @default.
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- W2005998541 date "1991-09-01" @default.
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- W2005998541 title "Isotope-dependent quenching of singlet molecular oxygen (1Δg) by ground-state oxygen in several perhalogenated solvents" @default.
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- W2005998541 doi "https://doi.org/10.1016/0009-2614(91)87176-c" @default.
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