FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2006018032> ?p ?o ?g. }

• W2006018032 endingPage "6514" @default.
• W2006018032 startingPage "6506" @default.
• W2006018032 abstract "The dissociative adsorption of C1–C4 alkanes on Ir(110)–(1×2) was investigated using supersonic molecular beam techniques. Three regimes of reactivity were observed. At incident kinetic energies less than 100 kJ/mol the dissociative adsorption probability for propane and butane increased to about 0.6 with both decreasing surface temperature and decreasing translational energy of the incident molecule suggesting that activation occured via trapping of the alkane on the surface. At kinetic energies below 110 kJ/mol for butane, 90 kJ/mol for propane, 60 kJ/mol for ethane, 40 kJ/mol for methane, and at elevated surface temperatures the reaction probabilities for alkanes were independent of surface temperature and translational energy, but increased significantly with the molecular weight or carbon chain length of the incident alkane. This behavior indicates an unactivated reaction channel for each species except methane. At kinetic energies above 110 kJ/mol for butane, 90 kJ/mol for propane, 60 kJ/mol for ethane, and 40 kJ/mol for methane the initial dissociative sticking probability increased with increasing translational energy and was independent of surface temperature, indicating direct translational activation of the incident alkane. The translational energy required to activate the incident alkane via this channel increased with carbon number or molecular weight, indicative of energy transfer processes that dissipate energy in the reactive collision. The dissipative transfer of translational energy out of the reactive channel via a hard cube collision with the surface accounts qualitatively for the increase in the apparent activation barrier with increasing molecular weight in this activated channel." @default.
• W2006018032 created "2016-06-24" @default.
• W2006018032 creator A5008404499 @default.
• W2006018032 creator A5042069920 @default.
• W2006018032 creator A5058684948 @default.
• W2006018032 date "1987-06-01" @default.
• W2006018032 modified "2023-09-24" @default.
• W2006018032 title "The dynamics of the dissociative adsorption of alkanes on Ir(110)" @default.
• W2006018032 cites W1972640926 @default.
• W2006018032 cites W1976081688 @default.
• W2006018032 cites W1980577175 @default.
• W2006018032 cites W1984204002 @default.
• W2006018032 cites W1995563029 @default.
• W2006018032 cites W2009663157 @default.
• W2006018032 cites W2010864934 @default.
• W2006018032 cites W2019799566 @default.
• W2006018032 cites W2020494127 @default.
• W2006018032 cites W2022146005 @default.
• W2006018032 cites W2026816107 @default.
• W2006018032 cites W2027969981 @default.
• W2006018032 cites W2036214111 @default.
• W2006018032 cites W2039637744 @default.
• W2006018032 cites W2039683258 @default.
• W2006018032 cites W2042273721 @default.
• W2006018032 cites W2044512373 @default.
• W2006018032 cites W2052737335 @default.
• W2006018032 cites W2052990095 @default.
• W2006018032 cites W2054872918 @default.
• W2006018032 cites W2059614474 @default.
• W2006018032 cites W2066004099 @default.
• W2006018032 cites W2069382051 @default.
• W2006018032 cites W2070580213 @default.
• W2006018032 cites W2071330627 @default.
• W2006018032 cites W2074377919 @default.
• W2006018032 cites W2075204595 @default.
• W2006018032 cites W2077594675 @default.
• W2006018032 cites W2078848877 @default.
• W2006018032 cites W2081468905 @default.
• W2006018032 cites W2084130327 @default.
• W2006018032 cites W2094928828 @default.
• W2006018032 cites W2100520141 @default.
• W2006018032 cites W2107823870 @default.
• W2006018032 cites W2136922551 @default.
• W2006018032 cites W4251471406 @default.
• W2006018032 cites W1978332834 @default.
• W2006018032 doi "https://doi.org/10.1063/1.452442" @default.
• W2006018032 hasPublicationYear "1987" @default.
• W2006018032 type Work @default.
• W2006018032 sameAs 2006018032 @default.
• W2006018032 citedByCount "96" @default.
• W2006018032 countsByYear W20060180322013 @default.
• W2006018032 countsByYear W20060180322014 @default.
• W2006018032 countsByYear W20060180322017 @default.
• W2006018032 countsByYear W20060180322019 @default.
• W2006018032 countsByYear W20060180322021 @default.
• W2006018032 countsByYear W20060180322022 @default.
• W2006018032 countsByYear W20060180322023 @default.
• W2006018032 crossrefType "journal-article" @default.
• W2006018032 hasAuthorship W2006018032A5008404499 @default.
• W2006018032 hasAuthorship W2006018032A5042069920 @default.
• W2006018032 hasAuthorship W2006018032A5058684948 @default.
• W2006018032 hasConcept C121332964 @default.
• W2006018032 hasConcept C135889238 @default.
• W2006018032 hasConcept C147789679 @default.
• W2006018032 hasConcept C150394285 @default.
• W2006018032 hasConcept C161790260 @default.
• W2006018032 hasConcept C178790620 @default.
• W2006018032 hasConcept C185592680 @default.
• W2006018032 hasConcept C2776345496 @default.
• W2006018032 hasConcept C2777207669 @default.
• W2006018032 hasConcept C2778717364 @default.
• W2006018032 hasConcept C2781327020 @default.
• W2006018032 hasConcept C516920438 @default.
• W2006018032 hasConcept C62520636 @default.
• W2006018032 hasConcept C75473681 @default.
• W2006018032 hasConcept C95121573 @default.
• W2006018032 hasConceptScore W2006018032C121332964 @default.
• W2006018032 hasConceptScore W2006018032C135889238 @default.
• W2006018032 hasConceptScore W2006018032C147789679 @default.
• W2006018032 hasConceptScore W2006018032C150394285 @default.
• W2006018032 hasConceptScore W2006018032C161790260 @default.
• W2006018032 hasConceptScore W2006018032C178790620 @default.
• W2006018032 hasConceptScore W2006018032C185592680 @default.
• W2006018032 hasConceptScore W2006018032C2776345496 @default.
• W2006018032 hasConceptScore W2006018032C2777207669 @default.
• W2006018032 hasConceptScore W2006018032C2778717364 @default.
• W2006018032 hasConceptScore W2006018032C2781327020 @default.
• W2006018032 hasConceptScore W2006018032C516920438 @default.
• W2006018032 hasConceptScore W2006018032C62520636 @default.
• W2006018032 hasConceptScore W2006018032C75473681 @default.
• W2006018032 hasConceptScore W2006018032C95121573 @default.
• W2006018032 hasIssue "11" @default.
• W2006018032 hasLocation W20060180321 @default.
• W2006018032 hasOpenAccess W2006018032 @default.
• W2006018032 hasPrimaryLocation W20060180321 @default.
• W2006018032 hasRelatedWork W2020863797 @default.
• W2006018032 hasRelatedWork W2073958796 @default.
• W2006018032 hasRelatedWork W2077773780 @default.

• next