FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2006019035> ?p ?o ?g. }

• W2006019035 endingPage "2042" @default.
• W2006019035 startingPage "2036" @default.
• W2006019035 abstract "This report presents a detailed investigation on the structural stability of the Au(25)(SG)(18) nanoclusters (where, -SG represents glutathionate) with a focus on the oxidation resistance and thermal stability of the Au-S bonds in the cluster. Two types of Au-S binding modes were previously indentified in the crystal structure of phenylethylthiolate-capped Au(25) clusters, and the Au(25)(SG)(18) nanoclusters have been confirmed to adopt the same structure as Au(25)(SCH(2)CH(2)Ph)(18) in our previous works. Herein, NMR in combination with optical spectroscopy revealed some distinct differences in both antioxidation and thermal stability of the two Au-S binding modes in the Au(25)(SG)(18) nanocluster, that is, the mode I thiolate ligands (total 12 ligands) exhibit a much higher stability than the mode II ligands (total 6 ligands). Upon the basis of this major observation as well as an abundant [Au(25)S(12)](-) species detected in laser desorption ionization (LDI) mass spectrometry analysis of Au(25)(SG)(18) clusters, a metastable species similar to Au(25)(SG)(12) (i.e., a loss of six type II ligands of -SG) may exist in the processes of oxidation and thermal treatment. Overall, this work provides a deep insight into the intriguing structure of thiolate-capped Au(25) clusters, which will benefit future studies pertaining to the potential applications of such nanoclusters." @default.
• W2006019035 created "2016-06-24" @default.
• W2006019035 creator A5020512076 @default.
• W2006019035 creator A5071069893 @default.
• W2006019035 date "2009-06-23" @default.
• W2006019035 modified "2023-09-26" @default.
• W2006019035 title "Stability of the Two Au−S Binding Modes in Au₂₅(SG)₁₈ Nanoclusters Probed by NMR and Optical Spectroscopy" @default.
• W2006019035 cites W1529850994 @default.
• W2006019035 cites W179471644 @default.
• W2006019035 cites W1965102508 @default.
• W2006019035 cites W1975320379 @default.
• W2006019035 cites W1976639056 @default.
• W2006019035 cites W1982099355 @default.
• W2006019035 cites W1982928139 @default.
• W2006019035 cites W1983735836 @default.
• W2006019035 cites W1984379455 @default.
• W2006019035 cites W1989456075 @default.
• W2006019035 cites W1989855030 @default.
• W2006019035 cites W1999341880 @default.
• W2006019035 cites W2001391601 @default.
• W2006019035 cites W2005762187 @default.
• W2006019035 cites W2007261624 @default.
• W2006019035 cites W2009317580 @default.
• W2006019035 cites W2011148933 @default.
• W2006019035 cites W2011703668 @default.
• W2006019035 cites W2017744970 @default.
• W2006019035 cites W2033514399 @default.
• W2006019035 cites W2034183695 @default.
• W2006019035 cites W2035946616 @default.
• W2006019035 cites W2039767749 @default.
• W2006019035 cites W2039904681 @default.
• W2006019035 cites W2040421848 @default.
• W2006019035 cites W2040857336 @default.
• W2006019035 cites W2043621883 @default.
• W2006019035 cites W2044605478 @default.
• W2006019035 cites W2044701233 @default.
• W2006019035 cites W2047822467 @default.
• W2006019035 cites W2049268949 @default.
• W2006019035 cites W2050307916 @default.
• W2006019035 cites W2054404247 @default.
• W2006019035 cites W2055738574 @default.
• W2006019035 cites W2060405283 @default.
• W2006019035 cites W2061666899 @default.
• W2006019035 cites W2062267147 @default.
• W2006019035 cites W2064375067 @default.
• W2006019035 cites W2064474620 @default.
• W2006019035 cites W2066175031 @default.
• W2006019035 cites W2066286007 @default.
• W2006019035 cites W2066673480 @default.
• W2006019035 cites W2068574350 @default.
• W2006019035 cites W2069807403 @default.
• W2006019035 cites W2072113036 @default.
• W2006019035 cites W2073578942 @default.
• W2006019035 cites W2074013888 @default.
• W2006019035 cites W2078754276 @default.
• W2006019035 cites W2086625758 @default.
• W2006019035 cites W2087726665 @default.
• W2006019035 cites W2087773611 @default.
• W2006019035 cites W2088725913 @default.
• W2006019035 cites W2089398769 @default.
• W2006019035 cites W2090046309 @default.
• W2006019035 cites W2090637288 @default.
• W2006019035 cites W2094683520 @default.
• W2006019035 cites W2095459615 @default.
• W2006019035 cites W2329132121 @default.
• W2006019035 cites W2329382411 @default.
• W2006019035 doi "https://doi.org/10.1021/nn9004999" @default.
• W2006019035 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19548695" @default.
• W2006019035 hasPublicationYear "2009" @default.
• W2006019035 type Work @default.
• W2006019035 sameAs 2006019035 @default.
• W2006019035 citedByCount "112" @default.
• W2006019035 countsByYear W20060190352012 @default.
• W2006019035 countsByYear W20060190352013 @default.
• W2006019035 countsByYear W20060190352014 @default.
• W2006019035 countsByYear W20060190352015 @default.
• W2006019035 countsByYear W20060190352016 @default.
• W2006019035 countsByYear W20060190352017 @default.
• W2006019035 countsByYear W20060190352018 @default.
• W2006019035 countsByYear W20060190352019 @default.
• W2006019035 countsByYear W20060190352020 @default.
• W2006019035 countsByYear W20060190352021 @default.
• W2006019035 countsByYear W20060190352022 @default.
• W2006019035 countsByYear W20060190352023 @default.
• W2006019035 crossrefType "journal-article" @default.
• W2006019035 hasAuthorship W2006019035A5020512076 @default.
• W2006019035 hasAuthorship W2006019035A5071069893 @default.
• W2006019035 hasConcept C115624301 @default.
• W2006019035 hasConcept C121332964 @default.
• W2006019035 hasConcept C162356407 @default.
• W2006019035 hasConcept C164866538 @default.
• W2006019035 hasConcept C171250308 @default.
• W2006019035 hasConcept C178790620 @default.
• W2006019035 hasConcept C185592680 @default.
• W2006019035 hasConcept C192562407 @default.
• W2006019035 hasConcept C199360897 @default.
• W2006019035 hasConcept C2778402822 @default.
• W2006019035 hasConcept C32891209 @default.

• next