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- W2006021963 abstract "The reactions of both ground, P3, and electronically excited, D1, oxygen atoms with hydrogen sulfide, H2S, have been investigated by means of the crossed molecular beams method with mass spectrometric detection at different collision energies. Amongst the possible reaction channels those leading to HSO+H for the O(3P) reaction and to HSO/HOS+H and SO+H2 for the O(1D) reaction have been identified and investigated. The dynamics of the channels leading to HSO/HOS+H are elucidated for the reactions of both states and the trend with increasing the collision energy analyzed. Noteworthily, the formation of SO+H2 products appears to be an open channel for the O(1D) reaction, at least for the highest collision energy investigated (11.8 kcal/mol). Finally, the recent experimental and theoretical estimates of the enthalpy of formation of the HSO radical have been critically analyzed to evaluate their conformity with the present experimental data." @default.
- W2006021963 created "2016-06-24" @default.
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- W2006021963 date "2004-05-06" @default.
- W2006021963 modified "2023-09-26" @default.
- W2006021963 title "Crossed beam studies of the reactions of atomic oxygen in the ground P3 and first electronically excited D1 states with hydrogen sulfide" @default.
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- W2006021963 doi "https://doi.org/10.1063/1.1714809" @default.
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