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- W2006043456 abstract "A theory for vibrational predissociation of hydrogen-bonden OH…O complexes via OH stretch-OO stretch energy transfer is constructed, motivated by a recent experiment on vibrational predissociation of hydrogen-bonded ethanol dimer in solution. The theory employs a vibrationally adiabatic perspective, exploiting the frequency separation between the OH and OO stretches. The nonadiabatic coupling responsible for the hydrogen bond rupture subsequent to OH stretch excitation is found analytically. A lifetime for ethanol dimer of ≈ 10 ps is estimated, which is within a factor of two of the experimental result. General trends are predicted and discussed for other OH…O complexes." @default.
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- W2006043456 date "1993-03-01" @default.
- W2006043456 modified "2023-10-16" @default.
- W2006043456 title "Vibrational predissociation in hydrogen-bonded OH…O complexes via OH stretch-OO stretch energy transfer" @default.
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- W2006043456 doi "https://doi.org/10.1016/0009-2614(93)85627-z" @default.
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