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• W2006057556 abstract "Ammoniated NH4 radicals produced by an ArF excimer laser photolysis of ammonia clusters are studied by one-photon ionization and time-of-flight mass spectroscopy. The ionization potentials (IPs) of NH4(NH3)n (n = 0–35) are determined by the photoionization threshold measurements. The binding energies of NH4 (NH3)n−1-NH3 (n = 1–6) are estimated from IPs. The results indicate that the bonding between NH4 and NH3 is semi-ionic. The IPs for larger clusters are found to decrease monotonically with increasing n to a limit of 1.33 eV, which coincides with the photoemission threshold of liquid NH3. This feature is similar to those found recently for alkali atoms-ammonia clusters." @default.
• W2006057556 created "2016-06-24" @default.
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• W2006057556 date "1994-11-01" @default.
• W2006057556 modified "2023-10-16" @default.
• W2006057556 title "Photoionization of hypervalent molecular clusters: electronic structure and stability of NH4 (NH3)" @default.
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• W2006057556 doi "https://doi.org/10.1016/0009-2614(94)01115-x" @default.
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