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• W2006057653 abstract "Abstract Dark maroon coloured single crystals of [ cis -Co(en) 2 (N 3 ) 2 ][ trans -Co(NH 3 ) 2 (NO 2 ) 4 ] were obtained by slowly mixing the separately dissolved [ cis -diazidobis(ethylenediamine)cobalt(III)] nitrate with potassium [ trans -diamminetetranitrocobaltate(III)] in aqueous medium in 1:1 molar ratio. The complex salt was characterized by elemental analyses, spectroscopic studies (IR, UV/visible, 1 H and 13 C NMR) and solubility product measurements. The title complex salt crystallises in triclinic space group P 1 ¯ having cell dimensions, a  = 7.4210(2), b  = 11.0618(3), c  = 12.3763(3) A, α  = 95.5850(10), β  = 91.4400(10), γ  = 108.9070(10)°, V  = 954.853 A 3 , Z  = 2 and R -factor = 5.16%. Single crystal X-ray structure determination revealed an ionic structure consisting of [ cis -Co(en) 2 (N 3 ) 2 ] + and [ trans -Co(NH 3 ) 2 (NO 2 ) 4 ] − . Supramolecular hydrogen bonding networks involving second sphere coordination like [ NH en + ⋯ X anion - ] besides electrostatic forces of attraction have been observed to stabilize the crystal lattice. This is the first crystal structure of a salt containing [ trans -diamminetetranitrocobaltate(III)] anion and [ cis -diazidobis(ethylenediamine)cobalt(III)] cation. The formation of complex salt of definite composition and solubility product measurements show that the cationic cobaltammine [ cis -Co(en) 2 (N 3 ) 2 ] + is a potential anion receptor for complex anion [ trans -Co(NH 3 ) 2 (NO 2 ) 4 ] − in aqueous medium." @default.
• W2006057653 created "2016-06-24" @default.
• W2006057653 creator A5016994463 @default.
• W2006057653 creator A5025604282 @default.
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• W2006057653 date "2008-08-01" @default.
• W2006057653 modified "2023-10-04" @default.
• W2006057653 title "Second sphere coordination in anion binding: Synthesis, characterization and X-ray structure of [cis-diazidobis(ethylenediamine)cobalt(III)][trans-diamminetetranitrocobaltate(III)]" @default.
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• W2006057653 doi "https://doi.org/10.1016/j.molstruc.2007.10.031" @default.
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