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- W2006075953 abstract "Allylation of carbonyl compounds with allyl halides mediated by a vanadium(II) complex in a mixed solvent system of THF and HMPA has been accomplished. The addition of HMPA stabilized a vanadium−carbon bond of an allyl vanadium species and prevented dimerization of allyl halides or pinacol coupling of carbonyl compounds. Other alkylations such as a benzylation of carbonyl compounds or a Reformatsky-type reaction could also be mediated by a low-valent vanadium(II) species and benzyl bromide or bromo acetate in a THF−HMPA solvent system. By isolation of the vanadium−HMPA complex, [V2Cl3(hmpa)6][ZnCl3(hmpa)] (HMPA = hexamethylphosphoric triamide), and clarification of its structure, it became clear that the coordination of bulky HMPA to vanadium centers played an important role in the carbon−carbon bond-forming reactions." @default.
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- W2006075953 date "1997-10-01" @default.
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- W2006075953 title "Stabilizing Effect of HMPA (Hexamethylphosphoric Triamide) on Vanadium−Carbon Bonds and Their Application to Carbon−Carbon Bond Formation Reactions" @default.
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- W2006075953 doi "https://doi.org/10.1021/om970545a" @default.
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