Matches in SemOpenAlex for { <https://semopenalex.org/work/W2006087162> ?p ?o ?g. }
- W2006087162 endingPage "1062" @default.
- W2006087162 startingPage "1062" @default.
- W2006087162 abstract "Synthetic supramolecular zipper complexes have been used to quantify substituent effects on the free energies of aromatic stacking interactions. The conformational properties of the complexes have been characterised using NMR spectroscopy in CDCl(3), and by comparison with the solid state structures of model compounds. The structural similarity of the complexes makes it possible to apply the double mutant cycle method to evaluate the magnitudes of 24 different aromatic stacking interactions. The major trends in the interaction energy can be rationalised using a simple model based on electrostatic interactions between the pi-faces of the two aromatic rings. However, electrostatic interactions between the substituents of one ring and the pi-face of the other make an additional contribution, due to the slight offset in the stacking geometry. This property makes aromatic stacking interactions particularly sensitive to changes in orientation as well as the nature and location of substituents." @default.
- W2006087162 created "2016-06-24" @default.
- W2006087162 creator A5029701197 @default.
- W2006087162 creator A5036384615 @default.
- W2006087162 creator A5040312166 @default.
- W2006087162 creator A5047219238 @default.
- W2006087162 creator A5049255628 @default.
- W2006087162 creator A5064693777 @default.
- W2006087162 creator A5065785380 @default.
- W2006087162 creator A5075603889 @default.
- W2006087162 creator A5076576877 @default.
- W2006087162 creator A5088695041 @default.
- W2006087162 date "2007-01-01" @default.
- W2006087162 modified "2023-10-14" @default.
- W2006087162 title "Substituent effects on aromatic stacking interactions" @default.
- W2006087162 cites W1889327667 @default.
- W2006087162 cites W1915442692 @default.
- W2006087162 cites W1964046622 @default.
- W2006087162 cites W1965519176 @default.
- W2006087162 cites W1965942439 @default.
- W2006087162 cites W1966304410 @default.
- W2006087162 cites W1966689737 @default.
- W2006087162 cites W1969031477 @default.
- W2006087162 cites W1969885133 @default.
- W2006087162 cites W1973981331 @default.
- W2006087162 cites W1974186810 @default.
- W2006087162 cites W1975206909 @default.
- W2006087162 cites W1980083592 @default.
- W2006087162 cites W1980097507 @default.
- W2006087162 cites W1983369380 @default.
- W2006087162 cites W1985627019 @default.
- W2006087162 cites W1986476601 @default.
- W2006087162 cites W1987290467 @default.
- W2006087162 cites W1987576577 @default.
- W2006087162 cites W1989028441 @default.
- W2006087162 cites W1991663757 @default.
- W2006087162 cites W1993672505 @default.
- W2006087162 cites W1996873419 @default.
- W2006087162 cites W1997787227 @default.
- W2006087162 cites W1999696019 @default.
- W2006087162 cites W1999698629 @default.
- W2006087162 cites W2002660107 @default.
- W2006087162 cites W2013359407 @default.
- W2006087162 cites W2018218383 @default.
- W2006087162 cites W2018832019 @default.
- W2006087162 cites W2026395206 @default.
- W2006087162 cites W2028105139 @default.
- W2006087162 cites W2028876885 @default.
- W2006087162 cites W2030153354 @default.
- W2006087162 cites W2032147538 @default.
- W2006087162 cites W2032477502 @default.
- W2006087162 cites W2038910677 @default.
- W2006087162 cites W2039788657 @default.
- W2006087162 cites W2039966881 @default.
- W2006087162 cites W2041361334 @default.
- W2006087162 cites W2045403572 @default.
- W2006087162 cites W2048631643 @default.
- W2006087162 cites W2052535057 @default.
- W2006087162 cites W2056791158 @default.
- W2006087162 cites W2058663932 @default.
- W2006087162 cites W2058760162 @default.
- W2006087162 cites W2061187359 @default.
- W2006087162 cites W2061729004 @default.
- W2006087162 cites W2062499278 @default.
- W2006087162 cites W2063650080 @default.
- W2006087162 cites W2064177983 @default.
- W2006087162 cites W2066897219 @default.
- W2006087162 cites W2067219399 @default.
- W2006087162 cites W2074246207 @default.
- W2006087162 cites W2075629977 @default.
- W2006087162 cites W2076990617 @default.
- W2006087162 cites W2077416151 @default.
- W2006087162 cites W2079919297 @default.
- W2006087162 cites W2081804011 @default.
- W2006087162 cites W2086416494 @default.
- W2006087162 cites W2088979606 @default.
- W2006087162 cites W2092826347 @default.
- W2006087162 cites W2098376669 @default.
- W2006087162 cites W2117858594 @default.
- W2006087162 cites W2123540673 @default.
- W2006087162 cites W2127822578 @default.
- W2006087162 cites W2136443677 @default.
- W2006087162 cites W2138333499 @default.
- W2006087162 cites W2139488497 @default.
- W2006087162 cites W2139509478 @default.
- W2006087162 cites W2142268071 @default.
- W2006087162 cites W2145602919 @default.
- W2006087162 cites W2150352263 @default.
- W2006087162 cites W2160790360 @default.
- W2006087162 cites W2171404207 @default.
- W2006087162 cites W2473296383 @default.
- W2006087162 cites W2574328790 @default.
- W2006087162 cites W2952250418 @default.
- W2006087162 cites W4238020961 @default.
- W2006087162 cites W4255886946 @default.
- W2006087162 cites W4319054864 @default.
- W2006087162 doi "https://doi.org/10.1039/b617576g" @default.
- W2006087162 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17377660" @default.