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• W2006088357 abstract "A highly efficient organocatalytic asymmetric SMA reaction of hexafluoroisopropyl α,β-unsaturated esters has been developed. Introducing electron-withdrawing hexafluoroisopropyl ester is crucial to enhancing the electrophilicity of unsaturated esters as SMA acceptors. The catalytic system performs well over a broad scope of α,β-unsaturated esters and diversified thiols and provides facile access to (R)-thiazesim in a one-pot protocol." @default.
• W2006088357 created "2016-06-24" @default.
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• W2006088357 date "2013-06-17" @default.
• W2006088357 modified "2023-10-18" @default.
• W2006088357 title "Organocatalytic Asymmetric Sulfa-Michael Addition of Thiols to α,β-Unsaturated Hexafluoroisopropyl Esters: Expeditious Access to (<i>R</i>)-Thiazesim" @default.
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• W2006088357 doi "https://doi.org/10.1021/ol4015305" @default.
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