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- W2006092476 abstract "Processes of thermooxidative degradation in oligo- and polymethylsilsesquioxanes under homogeneous conditions (powder) have been investigated, using methods of dynamic TGA and DTA as well as X-ray photoelectronic and Auger spectroscopy (XPS, AugS). The degradation accompanied by transformation of methyl radicals took place in the interval 300–600°C and proceeded in two stages relating to the reactions on the surface of the polymer film and in the volume. In the carrier-polymer film heterogeneous systems thermal transformations in the volume occurred at higher temperatures, starting at the carrier-polymer interface. This fact is due both to the effect of the silicon oxide layer formed on the external surface of the polymethylsilsesquioxane films (thus inhibiting the diffusion of oxygen), and also to the activating influence of the carrier. The energy of activation of thermal transformation of methyl radicals in the volume of the polymer film is equal to 290 kJ/mol, while at the carrier-polymer interface it is from 2 to 3 times lower." @default.
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- W2006092476 date "1990-01-01" @default.
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- W2006092476 title "Features of the structuralization appearing in oligo- and polymethylsilsesquioxanes in the course of the thermooxidative degradation" @default.
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- W2006092476 doi "https://doi.org/10.1016/0032-3950(90)90294-g" @default.
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