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- W2006095231 abstract "Abstract Second virial (A2) and preferential solvation (λ) coefficients, as well as binary interaction potential (g12), as measured by light scattering, for the system n-decane (1)-butanone (MEK) (2)-poly(dimethylsiloxane) (PDMS) (3) have been determined at 20°. The system displays cosolvency, as the inversion in λ and the maximum in A2 at φ 10 ⋍ 0.65 seem to indicate. ΔAmax2, defined as the difference between the “real” and “ideal” A2 values at the solvent mixture composition in which A2 attains its maximum value, is proposed as the most adequate parameter to define quantitatively the cosolvency degree in a ternary system. Theoretical ΔAmax2 values, as calculated through the Flory-Huggins (FH) formalism and the Pouchly generalized formalism (FHP), are compared to experimental values for diverse n-alkane-MEK-PDMS systems. Poor agreement is obtained between the sets of data if ternary interactions are neglected. Moreoever, through ax, the parameter correlating A2 experimental data, excess free energies for the solvent mixtures n-alkane-MEK are evaluated and also compared with fair agreement with the corresponding experimental values." @default.
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- W2006095231 date "1986-01-01" @default.
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- W2006095231 title "Cosolvency in n-alkane-butanone-poly(dimethylsiloxane) systems" @default.
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- W2006095231 doi "https://doi.org/10.1016/0014-3057(86)90107-2" @default.
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