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• W2006142425 abstract "Glass formation has been examined in the systems based on ZnI2. Glasses are obtained in ZnI2CsIMI2 (M  Ba, Pb) and ZnI2CsIBaI2M′I (M′  Tl, Ag) systems. Raman and far IR spectra have been measured for the ZnI2CsIBaI2 glasses and crystals of ZnI2 and Cs2ZnI4. Raman spectra of the glasses have two highly polarized bands at 113 cm−1 and 124 cm−1, while in far IR spectra strong and broad overlapping absorption bands at 152 cm−1, 173 cm−1 and 197 cm−1 are observed. A comparison with the spectra of ZnI2 and Cs2ZnI4 crystals indicates that the glasses have a structure consisting of ZnI4 tetrahedra sharing corners. The bands of the glasses are assigned as follows: the 113 cm−1 and 124 cm−1 bands are due to the symmetric modes containing stretching vibrations of Zn-bridging I(bI) and Zn-non-bridging I(nbI) of ZnI4 tetrahedra, respectively, and the 152 cm−1 and 197 cm−1 bands are due to the antisymmetric modes of the Zn-bI stretching vibration and the 173 cm−1 band to the antisymmetric mode of the Zn-nbI stretching vibration. These assignments are consistent with the compositional variations of the spectra." @default.
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• W2006142425 date "1990-01-01" @default.
• W2006142425 modified "2023-10-14" @default.
• W2006142425 title "Preparation and vibrational spectroscopy of ZnI2-based glasses" @default.
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• W2006142425 doi "https://doi.org/10.1016/0022-3093(90)91042-p" @default.
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