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- W2006142496 abstract "The relaxation of the segmental orientation and the chain extension in polycarbonate have been studied by infrared dichroism and heat shrinkage after a step strain deformation to a draw ratio of λ = 1.75. This makes it possible to distinguish between local relaxation mechanisms (Rouse) and large-scale relaxation mechanisms of the molecular orientation. It was found that the average relaxation time for segmental orientation is shorter and more temperature dependent than the average relaxation time for the chain extension. The segmental orientation relaxes almost totally at 170 °C (T g = 148 °C) before the chain extension even starts to relax." @default.
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- W2006142496 title "Relaxation of Segmental Orientation and Chain Extension in Polycarbonate Studied by Infrared Dichroism and Shrinkage" @default.
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- W2006142496 doi "https://doi.org/10.1021/ma9464433" @default.
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