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• W2006150390 abstract "The dynamic birefringence and intrinsic viscosity of polybutylisocyanate (PBIC) fractions in tetrachloromethane were investigated in a 400-fold range of molecular weights. The conformation of the PBIC molecules was found to vary from a straight rod to a Gaussian coil in the same solvent. The experimentally found relationship of [n/η]=f(M) was used for determination of the equilibrium rigidity of the molecules based on the optical data. The general shape of the experimental curve of [n]/[η]=f(M) is compared with existing birefringence theories for absolutely rigid and infinitely fine persistent chains." @default.
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• W2006150390 date "1974-01-01" @default.
• W2006150390 modified "2023-10-16" @default.
• W2006150390 title "The optical anisotropy and rigidity of polybutylisocyanate molecules" @default.
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• W2006150390 doi "https://doi.org/10.1016/0032-3950(74)90352-9" @default.
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