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• W2006165370 abstract "Surface tension of pure and mixed aqueous solutions of both inorganic and organic species that are relevant in atmospheric droplets has been studied in a laboratory investigation. Following the Gibbsian theory of surfaces experimental data have been fitted by the Szyszkowski equation. As a function of the carbon-chain length trends in the maximum surface excess Γmax and the inverse surface activity β have been clearly identified for pure aqueous solutions of homologous series of n-alcohols and mono-carboxylic acids, while these parameters oscillate for the homologous series of di-carboxylic acids. For mixed aqueous solutions of water-soluble organic and inorganic compounds, e.g. cis-pinonic acid and sodium chloride, a further decrease in surface tension has been observed, which can be interpreted as an interaction between the inorganic and organic solutes and an enrichment of the surface-active organic compound in the surface layer. Taking this effect into account surface-tension data of real atmospheric samples become more plausible, especially when also slightly soluble or water-insoluble organic compounds having a high surface activity at low concentrations are considered." @default.
• W2006165370 created "2016-06-24" @default.
• W2006165370 creator A5030282107 @default.
• W2006165370 date "2007-09-01" @default.
• W2006165370 modified "2023-10-13" @default.
• W2006165370 title "Surface tension of aqueous solutions of water-soluble organic and inorganic compounds" @default.
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• W2006165370 doi "https://doi.org/10.1016/j.atmosenv.2007.03.051" @default.
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