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- W2006170490 abstract "Abstract H 2 S removal using Ca ion-exchanged coal char was studied in a fixed bed reactor at a temperature of 900°C. Yallourn, an Australian brown coal was used for ion exchange. The CaO obtained from the pyrolysis of Ca ion-exchanged coal was finely dispersed in the char and much more reactive toward H 2 S than that from limestone. Ca ion-exchanged coal char showed high H 2 S capture and almost no emission of H 2 S was observed in the earlier reaction stage. At a reaction time of 100 min, the S/Ca atomic ratio in Ca ion-exchanged coal char increased to 1.2. This was due to H 2 S capture capacity of both the coal char itself and the CaO distributed in the char. The sorption capacity of char was determined as 1.5 mmol-H 2 S/g-char. The desulfurization characteristics of calcined limestone strongly depended on the particle size, whereas those of Ca ion-exchanged coal char was almost independent of the char particle size." @default.
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- W2006170490 title "Ca ion-exchanged coal char as H2S sorbent" @default.
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