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- W2006181589 abstract "An asymmetric Schiff base, H2L, has been prepared by condensation of the selectively functionalised 2-(tosylaminomethyl)aniline (A) with 2-tosylaminobenzaldehyde (B). H2L has been characterised by elemental analysis, FAB-MS, NMR and FTIR techniques. The molecular structure of A has been elucidated by X-ray diffraction methods, as well as four different conformational isomers of H2L, which are present in the three polymorphic forms solved (Ta, Tc and M). Two of these polymorphs (Tc and M) are based on similar dimeric units, which are connected via two intermolecular N–H⋯O bonds, along with some edge-to-face and face-to-face interactions. Molecules corresponding to Ta are differently conformed, and display two intramolecular N–H⋯O and N–H⋯N bonds. In this crystal structure, pairs of neighbouring molecules are connected through simultaneous face-to-face interactions between their two tosyl groups." @default.
- W2006181589 created "2016-06-24" @default.
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- W2006181589 date "2007-01-01" @default.
- W2006181589 modified "2023-10-18" @default.
- W2006181589 title "Trimorphism of an asymmetric disulfonamide Schiff base" @default.
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- W2006181589 doi "https://doi.org/10.1039/b704195k" @default.
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