Matches in SemOpenAlex for { <https://semopenalex.org/work/W2006183238> ?p ?o ?g. }
- W2006183238 endingPage "2077" @default.
- W2006183238 startingPage "2074" @default.
- W2006183238 abstract "Five-membered zirconacycles were generated in a new way, by simultaneously reducing Cp2ZrCl2 and di- or tetrahalogenoalkanes with La or mischmetall (an alloy of lanthanides) at room temperature. Zirconacyclopentane, formed by using 1,2-diiodoethane as an ethylene source, underwent ligand exchange with diphenylacetylene to afford the corresponding zirconacyclopentene and zirconacyclopentadiene complexes. Reaction monitoring with diphenylacetylene by GC-MS spectroscopy indicated that not only did the usual ligand exchange occur but also a direct homocoupling with a La-derived Cp2Zr equivalent could take place. Unsubstituted zirconacyclopentadiene, unavailable by classic methods, was formed by using tetrabromoethane as an acetylene source. It reacted with monosubstituted alkynes, in the absence of Cu or Ni additives, to afford monosubstituted benzene derivatives." @default.
- W2006183238 created "2016-06-24" @default.
- W2006183238 creator A5004778475 @default.
- W2006183238 creator A5028485269 @default.
- W2006183238 creator A5034830055 @default.
- W2006183238 creator A5064365404 @default.
- W2006183238 date "2008-03-21" @default.
- W2006183238 modified "2023-10-13" @default.
- W2006183238 title "Reaction of Lanthanides (La, Mischmetall) with Cp<sub>2</sub>ZrCl<sub>2</sub> and Di- or Tetrahalogenoalkanes: New Formation and Studies of Five-Membered Zirconacycles" @default.
- W2006183238 cites W1966504506 @default.
- W2006183238 cites W1976431949 @default.
- W2006183238 cites W1980201444 @default.
- W2006183238 cites W1980693907 @default.
- W2006183238 cites W1985757638 @default.
- W2006183238 cites W1999798695 @default.
- W2006183238 cites W2010648263 @default.
- W2006183238 cites W2025616884 @default.
- W2006183238 cites W2028556061 @default.
- W2006183238 cites W2031551851 @default.
- W2006183238 cites W2041712430 @default.
- W2006183238 cites W2042619453 @default.
- W2006183238 cites W2044326919 @default.
- W2006183238 cites W2049392986 @default.
- W2006183238 cites W2052272098 @default.
- W2006183238 cites W2062975057 @default.
- W2006183238 cites W2082416998 @default.
- W2006183238 cites W2092866252 @default.
- W2006183238 cites W2094288741 @default.
- W2006183238 cites W2111545058 @default.
- W2006183238 cites W2144453205 @default.
- W2006183238 cites W2170517170 @default.
- W2006183238 cites W2949563973 @default.
- W2006183238 cites W2950024182 @default.
- W2006183238 cites W2950288248 @default.
- W2006183238 cites W2951099745 @default.
- W2006183238 cites W2952761522 @default.
- W2006183238 cites W575392521 @default.
- W2006183238 doi "https://doi.org/10.1021/om701217e" @default.
- W2006183238 hasPublicationYear "2008" @default.
- W2006183238 type Work @default.
- W2006183238 sameAs 2006183238 @default.
- W2006183238 citedByCount "6" @default.
- W2006183238 countsByYear W20061832382015 @default.
- W2006183238 countsByYear W20061832382022 @default.
- W2006183238 crossrefType "journal-article" @default.
- W2006183238 hasAuthorship W2006183238A5004778475 @default.
- W2006183238 hasAuthorship W2006183238A5028485269 @default.
- W2006183238 hasAuthorship W2006183238A5034830055 @default.
- W2006183238 hasAuthorship W2006183238A5064365404 @default.
- W2006183238 hasConcept C116569031 @default.
- W2006183238 hasConcept C145148216 @default.
- W2006183238 hasConcept C155647269 @default.
- W2006183238 hasConcept C161790260 @default.
- W2006183238 hasConcept C170493617 @default.
- W2006183238 hasConcept C178790620 @default.
- W2006183238 hasConcept C185592680 @default.
- W2006183238 hasConcept C201770740 @default.
- W2006183238 hasConcept C2777517455 @default.
- W2006183238 hasConcept C2777691172 @default.
- W2006183238 hasConcept C2778597550 @default.
- W2006183238 hasConcept C2780446808 @default.
- W2006183238 hasConcept C2781019423 @default.
- W2006183238 hasConcept C44228677 @default.
- W2006183238 hasConcept C521977710 @default.
- W2006183238 hasConcept C55493867 @default.
- W2006183238 hasConceptScore W2006183238C116569031 @default.
- W2006183238 hasConceptScore W2006183238C145148216 @default.
- W2006183238 hasConceptScore W2006183238C155647269 @default.
- W2006183238 hasConceptScore W2006183238C161790260 @default.
- W2006183238 hasConceptScore W2006183238C170493617 @default.
- W2006183238 hasConceptScore W2006183238C178790620 @default.
- W2006183238 hasConceptScore W2006183238C185592680 @default.
- W2006183238 hasConceptScore W2006183238C201770740 @default.
- W2006183238 hasConceptScore W2006183238C2777517455 @default.
- W2006183238 hasConceptScore W2006183238C2777691172 @default.
- W2006183238 hasConceptScore W2006183238C2778597550 @default.
- W2006183238 hasConceptScore W2006183238C2780446808 @default.
- W2006183238 hasConceptScore W2006183238C2781019423 @default.
- W2006183238 hasConceptScore W2006183238C44228677 @default.
- W2006183238 hasConceptScore W2006183238C521977710 @default.
- W2006183238 hasConceptScore W2006183238C55493867 @default.
- W2006183238 hasIssue "9" @default.
- W2006183238 hasLocation W20061832381 @default.
- W2006183238 hasOpenAccess W2006183238 @default.
- W2006183238 hasPrimaryLocation W20061832381 @default.
- W2006183238 hasRelatedWork W1984200272 @default.
- W2006183238 hasRelatedWork W2030404698 @default.
- W2006183238 hasRelatedWork W2039069155 @default.
- W2006183238 hasRelatedWork W2053249882 @default.
- W2006183238 hasRelatedWork W2081682267 @default.
- W2006183238 hasRelatedWork W2083533959 @default.
- W2006183238 hasRelatedWork W2113415107 @default.
- W2006183238 hasRelatedWork W3156766956 @default.
- W2006183238 hasRelatedWork W3165052366 @default.
- W2006183238 hasRelatedWork W317975445 @default.
- W2006183238 hasVolume "27" @default.
- W2006183238 isParatext "false" @default.
- W2006183238 isRetracted "false" @default.