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- W2006185831 abstract "Abstract High pressure behaviors of nanoporous anatase TiO 2 were studied using in situ Raman spectroscopy up to 37 GPa. The nanoporous anatase phase starts to transform into the baddeleyite phase with poor crystallinity at ∼15.2 GPa, and the baddeleyite phase coexists with anatase phase up to 18.4 GPa. The baddeleyite form transforms into an amorphous phase above 20.5 GPa. Upon decompression, the amorphous phase recovers to the baddeleyite phase and then transforms to the α-PbO 2 phase. The phase transition from the baddeleyite phase to the amorphous form is reversible. The poor crystalline baddeleyite phase acts as an intermediate state in the amorphization process. The phase transitions of the nanoporous anatase TiO 2 are obviously different from the pressure-induced amorphization in the anatase TiO 2 nanoparticles. These results indicate that the porous microstructure plays important roles in the high pressure phase transitions of the nanoporous anatase TiO 2 ." @default.
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- W2006185831 date "2012-06-01" @default.
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- W2006185831 title "High pressure behaviors of nanoporous anatase TiO2" @default.
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- W2006185831 doi "https://doi.org/10.1016/j.materresbull.2012.03.002" @default.
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