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- W2006199322 abstract "The bakers' yeast reduction of trifluoroacetyl derivatives was examined in the presence of various esters of methanethiosulfonate. The yeast reduction of 4-bromo-4′-trifluoroacetylbiphenyl using the cyclohexylmethyl methanethiosulfonate resulted in the R product with the highest enantiomeric excess of 96% ee, which is compared with the reduction without the additive to give the corresponding alcohol with 84% ee. On the other hand, in the case of 4-hyrdoxy-4′-trifluoroacetylbiphenyl, the highest enantioselectivity was observed also using cyclohexylmethyl methanethiosulfonate to give the R-product with 90% ee, in contrast with the reduction without the additives to give the same product with 77% ee." @default.
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- W2006199322 date "1999-03-01" @default.
- W2006199322 modified "2023-09-23" @default.
- W2006199322 title "Enantiocontrol in the bakers' yeast reduction of trifluoroacetylbiphenyl derivatives" @default.
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- W2006199322 doi "https://doi.org/10.1016/s0040-4039(99)00052-0" @default.
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