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- W2006206199 abstract "The phase transitions of crystalline NH4NO3 are studied through the analysis of the variation of the Raman intensities IR of the nitrate ν1 mode in the critical regions. Critical exponent β can be elucidated through the fitting of IR with /vbT − TC/vbβ. It is demonstrated that β is related to the thermodynamic quantities of the phase transitions. The analysis after an exponential model is explored giving rather suggestive results. Another parameter, the ratio of the pre-exponential factors in the exponential model which can only be elucidated through both the spectroscopic and thermodynamic quantities for the low and high temperature phases is also introduced. It is demonstrated that this parameter could bear much important information of the phase transitions as far as the degree of the structural order of the critical regions is concerned." @default.
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- W2006206199 title "The critical Raman intensity behavior of the nitrate ν1 mode and its thermodynamic interpretation for the phase transitions of crystalline NH4NO3" @default.
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- W2006206199 doi "https://doi.org/10.1016/0584-8539(94)00141-w" @default.
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